The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma     

Stephen J. Barnes  J. A. C. Anderson  T. R. Smith  L. Bagas 《Mineralium Deposita》2008,43(6):641-662

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Fluid and source magma evolution of the Questa porphyry Mo deposit,New Mexico,USA   总被引：14，自引：1，他引：13  

Leonhard M. Klemm  Thomas Pettke  Christoph A. Heinrich 《Mineralium Deposita》2008,43(5):533-552

Combined fluid inclusion microthermometry and microanalysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) are used to constrain the hydrothermal processes forming a typical Climax-type porphyry Mo deposit. Molybdenum mineralisation at Questa occurred in two superimposed hydrothermal stages, a magmatic-hydrothermal breccia and later stockwork veining. In both stages, texturally earliest fluids were single-phase, of low salinity (~7 wt.% NaCl_equiv.) and intermediate-density. Upon decompression to ~300 bar, they boiled off a vapour phase, leaving behind a residual brine (up to 45 wt.% NaCl_equiv) at temperatures of ~420°C. The highest average Mo concentrations in this hot brine were ~500 μg/g, exceeding the Mo content of the intermediate-density input fluid by about an order of magnitude and reflecting pre-concentration of Mo by fluid phase separation prior to MoS₂ deposition from the brine. Molybdenum concentrations in brine inclusions, then, decrease down to 5 μg/g, recording Mo precipitation in response to cooling of the saline liquid to ~360°C. Molybdenite precipitation from a dense, residual and probably sulphide-depleted brine is proposed to explain the tabular shape of the ore body and the absence of Cu-Fe sulphides in contrast to the more common Cu-Mo deposits related to porphyry stocks. Cesium and Rb concentrations in the single-phase fluids of the breccia range from 2 to 8 and from 40 to 65 μg/g, respectively. In the stockwork veins, Cs and Rb concentrations are significantly higher (45–90 and 110–230 μg/g, respectively). Because Cs and Rb are incompatible and hydrothermally non-reactive elements, the systematic increase in their concentration requires two distinct pulses of fluid exsolution from a progressively more fractionated magma. By contrast, major element and ore metal concentrations of these two fluid pulses remain essentially constant. Mass balance calculations using fluid chemical data from LA-ICPMS suggest that at least 25 km³ of melt and 7 Gt of deep input fluid were necessary to provide the amount of Mo contained in the stockwork vein stage alone. While the absolute amounts of fluid and melt are uncertain, the well-constrained element ratios in the fluids together with empirical fluid/melt partition coefficients derived from the inclusion analyses suggest a high water content of the source melt of ~10%. In line with other circumstantial evidence, these results suggest that initial fluid exsolution may have occurred at a confining pressure exceeding 5 kbar. The source of the molybdenum-mineralising fluids probably was a particularly large magma chamber that crystallised and fractionated in the lower crust or at mid-crustal level, well below the shallow intrusions immediately underlying Questa and other porphyry molybdenum deposits. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating     

Mirta Garrido  Fernando Barra  Eduardo Domínguez  Joaquin Ruiz  Victor A. Valencia 《Mineralium Deposita》2008,43(5):591-597

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.  相似文献   

East Asian monsoon variation and climate changes in Jeju Island, Korea, during the latest Pleistocene to early Holocene     

Seung Hyoun Lee  Yong Il Lee  Ho Il Yoon 《Quaternary Research》2008,70(2):265-274

A 4.96-m-long sediment core from the Hanon paleo-maar in Jeju Island, Korea was studied to investigate the paleoclimatic change and East Asian monsoon variations during the latest Pleistocene to early Holocene (23,000-9000 cal yr BP). High-resolution TOC content, magnetic susceptibility, and major element composition data indicate that Jeju Island experienced the coldest climate around 18,000 cal yr BP, which corresponds to the last glacial maximum (LGM). Further, these multi-proxy data show an abrupt shift in climatic regime from cold and arid to warm and humid conditions at around 14,000 cal yr BP, which represents the commencement of the last major deglaciation. After the last major deglaciation, the TOC content decreased from 13,300 to 12,000 cal yr BP and from 11,500 to 9800 cal yr BP, thereby reflecting the weakening of the summer monsoon. The LGM in Jeju Island occurred later in comparison with the Chinese Loess Plateau. Such a disparity in climatic change events between central China and Jeju Island appears to be caused by the asynchrony between the coldest temperature event and the minimum precipitation event in central China and by the buffering effect of the Pacific Ocean.  相似文献   

Extensional Late Paleozoic deformation on the western margin of Pangea, Patlanoaya area, Acatlán Complex, southern Mexico     

M.A. Ramos-Arias  J.D. Keppie  A. Ortega-Rivera  J.W.K. Lee 《Tectonophysics》2008,448(1-4):60-76

New mapping in the northern part of the Paleozoic Acatlán Complex (Patlanoaya area) records several ductile shear zones and brittle faults with normal kinematics (previously thought to be thrusts). These movement zones separate a variety of units that pass structurally upwards from: (i) blueschist-eclogitic metamorphic rocks (Piaxtla Suite) and mylonitic megacrystic granites (Columpio del Diablo granite ≡ Ordovician granites elsewhere in the complex); (ii) a gently E-dipping, listric, normal shear zone with top to the east kinematic indicators that formed under upper greenschist to lower amphibolite conditions; (iii) the Middle–Late Ordovician Las Minas quartzite (upper greenschist facies psammites with minor interbedded pelites intruded by mafic dikes and a leucogranite dike from the Columpio del Diablo granite) unconformably overlain by the Otate meta-arenite (lower greenschist facies psammites and pelites): roughly temporal equivalents are the Middle–Late Ordovician Mal Paso and Ojo de Agua units (interbedded metasandstone and slate, and metapelite and mafic minor intrusions, respectively) — some of these units are intruded by the massive, 461 ± 2 Ma, Palo Liso megacrystic granite: decussate, contact metamorphic muscovite yielded a ⁴⁰Ar/³⁹Ar plateau age of 440 ± 4 Ma; (iv) a steeply-moderately, E-dipping normal fault; (v) latest Devonian–Middle Permian sedimentary rocks (Patlanoaya Group: here elevated from formation status). The upward decrease in metamorphic grade is paralleled by a decrease in the number of penetrative fabrics, which varies from (i) three in the Piaxtla Suite, through (ii) two in the Las Minas unit (E-trending sheath folds deformed by NE-trending, subhorizontal folds with top to the southeast asymmetry, both associated with a solution cleavage), (iii) one in the Otate, Mal Paso, and Ojo de Agua units (steeply SE-dipping, NE–SW plunging, open-close folds), to (iv) none in the Patlanoaya Group. ⁴⁰Ar/³⁹Ar analyses of muscovite from the earliest cleavage in the Las Minas unit yielded a plateau age of 347 ± 3 Ma and show low temperature ages of  260 Ma. Post-dating all of these structures and the Patlanoaya Group are NE-plunging, subvertical folds and kink bands. An E–W, vertical normal fault juxtaposes the low-grade rocks against the Anacahuite amphibolite that is cut by megacrystic granite sheets, both of which were deformed by two penetrative fabrics. Amphibole from this unit has yielded a ⁴⁰Ar/³⁹Ar plateau age of 299 ± 6 Ma, which records cooling through  490 °C and is probably related to a Permo-Carboniferous reheating event during exhumation. The extensional deformation is inferred to have started in the latest Devonian ( 360 Ma) during deposition of the basal Patlanoaya Group, lasting through the rapid exhumation of the Piaxtla Suite at  350–340 Ma synchronous with cleavage development in the Las Minas unit, deposition of the Patlanoaya Group with active fault-related exhumation suggested by Mississippian and Early Permian conglomerates ( 340 and 300 Ma, respectively), and continuing at least into the Middle Permian (≡ 260 Ma muscovite ages). The continuity of Mid-Continent Mississippian fauna from the USA to southern Mexico suggests that this extensional deformation occurred on the western margin of Pangea after closure of the Rheic Ocean.  相似文献   

Magnetotelluric investigations for imaging electrical structure of Garhwal Himalayan corridor,Uttarakhand, India     

M. Israil  D. K. Tyagi  P. K. Gupta  Sri Niwas 《Journal of Earth System Science》2008,117(3):189-200

Magnetotelluric investigations have been carried out in the Garhwal Himalayan corridor to delineate the electrical structure of the crust along a profile extending from Indo-Gangetic Plain to Higher Himalayan region in Uttarakhand, India. The profile passing through major Himalayan thrusts: Himalayan Frontal Thrust (HFF), Main Boundary Thrust (MBT) and Main Central Thrust (MCT), is nearly perpendicular to the regional geological strike. Data processing and impedance analysis indicate that out of 44 stations MT data recorded, only 27 stations data show in general, the validity of 2D assumption. The average geoelectric strike, N70°W, was estimated for the profile using tensor decomposition. 2D smooth geoelectrical model has been presented, which provides the electrical image of the shallow and deeper crustal structure. The major features of the model are (i) a low resistivity (<50Ωm), shallow feature interpreted as sediments of Siwalik and Indo-Gangetic Plain, (ii) highly resistive (> 1000Ωm) zone below the sediments at a depth of 6 km, interpreted as the top surface of the Indian plate, (iii) a low resistivity (< 10Ωm) below the depth of 6 km near MCT zone coincides with the intense micro-seismic activity in the region. The zone is interpreted as the partial melting or fluid phase at mid crustal depth. Sensitivity test indicates that the major features of the geoelectrical model are relevant and desired by the MT data.  相似文献   

Paleosol at the Archean—Proterozoic contact in NW India revisited: Evidence for oxidizing conditions during paleo-weathering?     

Manoj K. Pandit  Helga de Wall  Narendra K. Chauhan 《Journal of Earth System Science》2008,117(3):201-209

A number of fine-grained sericite bearing pelitic, schistose lithologies occur along the Archean (Banded Gneiss Complex)-Proterozoic (Aravalli Supergroup) contact (APC) in the Udaipur valley in NW Indian craton. These Al-rich lithologies (subsequently metamorphosed) have been described as ‘paleosols’, developed over a 3.3 Ga old Archean gneissic basement and are overlain by Paleoproterozoic Aravalli quartzite. The paleosol was developed between 2.5 and 2.1, coincident with the globally recognized Great Oxidation Event (GOE). In previous studies these paleosol sections were interpreted to have developed under reducing environment, however, the finding of a ‘ferricrete’ zone in the upper part of Tulsi Namla section (east of Udaipur) during the present study (in addition to earlier reported lithologies) has led to an alternative suggestion of oxygen-rich conditions during paleosol development. The Tulsi Namla paleosol section shows all the features characteristic of a complete paleosol section described from other Archean cratons. The paleosol includes sericite schist with kyanite as the prevalent Al-silicate in the lower part of profile while chloritoid and Fe-oxides typify the Fe-rich upper part. Alumina has remained immobile during the weathering process while Fe and Mn show a decrease in the lower part of the section and an abrupt rise in the upper part, in the ferricrete zone. The field and geochemical data indicate that the Tulsi Namla section is an in situ weathering profile and at least the upper part shows evidence of oxidizing conditions.  相似文献   

Characteristics of spectral aerosol optical depths over India during ICARB     

S. Naseema Beegum  K. Krishna Moorthy  Vijayakumar S. Nair  S. Suresh Babu  S. K. Satheesh  V. Vinoj  R. Ramakrishna Reddy  K. Rama Gopal  K. V. S. Badarinath  K. Niranjan  Santosh Kumar Pandey  M. Behera  A. Jeyaram  P. K. Bhuyan  M. M. Gogoi  Sacchidanand Singh  P. Pant  U. C. Dumka  Yogesh Kant  J. C. Kuniyal  Darshan Singh 《Journal of Earth System Science》2008,117(1):303-313

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.  相似文献   

Aerosol mass loading over the marine environment of Arabian Sea during ICARB: Sea-salt and non-sea-salt components     

Susan K. George  Prabha R. Nair 《Journal of Earth System Science》2008,117(1):333-344

Mass loading and chemical composition of atmospheric aerosols over the Arabian Sea during the pre-monsoon months of April and May have been studied as a part of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB). These investigations show large spatial variabilities in total aerosol mass loading as well as that of individual chemical species. The mass loading is found to vary between 3.5 and 69.2 μg m^?3, with higher loadings near the eastern and northern parts of Arabian Sea, which decreases steadily to reach its minimum value in the mid Arabian Sea. The decrease in mass loading from the coast of India towards west is estimated to have a linear gradient of 1.53 μg m^?3/° longitude and an e^?1 scale distance of ～2300 km. SO ₄ ^2? , Cl^? and Na⁺ are found to be the major ionic species present. Apart from these, other dominating watersoluble components of aerosols are NO ₃ ^? (17%) and Ca²⁺ (6%). Over the marine environment of Arabian Sea, the non-sea-salt component dominates accounting to ～76% of the total aerosol mass. The spatial variations of the various ions are examined in the light of prevailing meteorological conditions and airmass back trajectories.  相似文献   

A technical note on seismic microzonation in the central United States     

Zhenming Wang 《Journal of Earth System Science》2008,117(2):749

Microzonation is an effort to evaluate and map potential hazards found in an area, urban area in particular, that could be induced by strong ground shaking during an earthquake. These hazards include: ground motion amplification, liquefaction, and slope failure. The microzonation maps, depicting ground-motion amplification, liquefaction, and landslide potentials, can be produced if the ground motion on bedrock (input) and the site conditions are known. These maps, in combination with ground-motion hazard maps (on bedrock), can be used to develop a variety of hazard mitigation strategies such as seismic risk assessment, emergency response and preparedness, and land-use planning. However, these maps have certain limitations that result from the nature of regional mapping, data limitations, generalization, and computer modeling. These microzonations show that when strong ground shaking occurs, damage is more likely to occur, or be more severe, in the higher hazard areas. The zones shown on the hazard maps should not serve as a substitute for site-specific evaluations.  相似文献